Journal of the Chemical Society. Chemical communications p. 1093 - 1095 (1983)
Update date:2022-08-30
Topics:
Bridges, Alexander J.
Fedij, Victor
Turowski, Eugene C.
3-Methyl-1-phenylthio-1-trimethylsilylbuta-1,2-diene (3) reacts with different alkyl-lithium reagents by C-Si or C-S bond cleavage, rather than by Michael addition or metallation; one product, the α-silyl-α-lithioallene (6), is alkylated mainly γ with carbonyl compounds, but is silylated α with Et3SiCl to form the 1,1-bis-silylallene Me2C=C=C(SiEt3)SiMe3.
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(1983)
