Journal of the Chemical Society. Chemical communications p. 1093 - 1095 (1983)
Update date:2022-08-30
Topics:
Bridges, Alexander J.
Fedij, Victor
Turowski, Eugene C.
3-Methyl-1-phenylthio-1-trimethylsilylbuta-1,2-diene (3) reacts with different alkyl-lithium reagents by C-Si or C-S bond cleavage, rather than by Michael addition or metallation; one product, the α-silyl-α-lithioallene (6), is alkylated mainly γ with carbonyl compounds, but is silylated α with Et3SiCl to form the 1,1-bis-silylallene Me2C=C=C(SiEt3)SiMe3.
View MoreCerametek Materials（ShenZhen）Co., Ltd.
Contact:+86-755-2324.2554
Address:A3-#9, YongChuan Street, Suite 501
Shandong united-rising pharmaceutical cooperation.,ltd.
Contact:008653187965009
Address:171No., Jing5 Road, Shizhong District, Jinan, China
Contact:+86-574- 87178138; 87297407
Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd
Contact:+86-533-5415882
Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Shijiazhuang Haotian Chemical Co., Ltd.
Contact:86-311-85044374
Address:293 Donggang Road
Doi:10.1039/c4ob01535e
(2015)Doi:10.1016/j.jorganchem.2012.07.042
(2012)Doi:10.1016/j.jcat.2004.01.009
(2004)Doi:10.1002/anie.201307193
(2013)Doi:10.1016/j.tetlet.2010.06.028
(2010)Doi:10.1016/S0040-4039(00)81315-5
(1983)
