Journal of Organic Chemistry p. 2712 - 2716 (1986)
Update date:2022-08-11
Topics:
Jones, Tappey H.
Highet, Robert J.
Don, Warwick A.
Blum, Murray S.
The major alkaloidal component from the ant Chelaner antarcticus (White) was found to be (5E,8Z)-3-(1-non-8-enyl)-5-((E)-1-prop-1-enyl)pyrrolizidine (1).The structure was suggested by spectral data and confirmed by a nonstereoselective synthesis, which also permitted the assignment of its stereochemistry.A minor component was the known compound trans-2-(1-hex-5-enyl)-5-(1-non-8-enyl)pyrrolidine (2), previously reported in Monomorium species.
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