Rhodium-catalyzed Si-F exchange reaction between fluorobenzenes and a disilane. Catalytic reaction involving cleavage of C-F bonds

DOI: 10.1246/cl.1998.157

Source and publish data:

Chemistry Letters p. 157 - 158 (1998)

Update date:2022-08-16

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Authors:

Ishii, Yutaka

Chatani, Naoto

Yorimitsu, Shuhei

Murai, Shinji

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Article abstract of DOI:10.1246/cl.1998.157

The reaction of functionalized fluorobenzenes, such as fluoroacetophenones and (fluorophenyl)oxazolines, with Me₃SiSiMe₃ in the presence of a catalytic amount of a rhodium complex results in a site-selective Si-F exchange to give ort

Full text of DOI:10.1246/cl.1998.157

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