Journal of Organic Chemistry p. 3408 - 3412 (1982)
Update date:2022-08-11
Topics:
Fox, Marye Anne
Campbell, Kay A.
Huenig, Siegfried
Berneth, Horst
Maier, Guenther
et al.
Cyclic voltammetric oxidation of tetra-tert-butyltetrahedrane (1;Epa = 0.50 +/- 0.10 V vs.SCE) is irreversible, producing the radical cation of tetra-tert-butylcyclobutadiene.No evidence for transient formation of other stable cation radical intermediates could be obtained in the electrooxidation of 1 and its subsequent formation of 2 radical cation.The oxidation is a one-electron process, and no waves attributable to redox reactions of the dication or dianion of cyclobutadiene could be observed.
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