Chemiluminescence and catalysis of the decomposition of dispiro(diadamantane-l,2-dioxetane) in solutions of lanthanide perchlorates 1: Catalysis of the 1,2-dioxetane decomposition

Article abstract of DOI:10.1007/BF01435381

Decomposition of dispiro(diadamantane-l,2-dioxetane) u1, Cd1, Tb1, Pr1, and Ce1 perchlorates was studied by the chemiluminescencc method. The rate constants of decomposition of 1 in complexes of composition 1 Ln"1 and stability constants of these complexes, as well as activation parameters of the decomposition of 1 and thermodynamic parameters of the complexation were determined. A correlation between the thermodynamic parameters of complexation and ionic radii of Ln"1 was found.