Diels-Alder Reactions of a Bicyclic, Cross-Conjugated Dienone

DOI: 10.1021/jo00018a028

Source and publish data:

Journal of Organic Chemistry p. 5353 - 5356 (1991)

Update date:2022-08-25

Topics:

Authors:

Alunni, Sergio

Minuti, Lucio

Pasciuti, Patrizia

Taticchi, Aldo

Guo, Ming

Wenkert, Ernest

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Article abstract of DOI:10.1021/jo00018a028

Aluminium chloride catalyzed Diels-Alder reactions of a bicyclic dienone of the 2,5-cyclohexadienone type with 1,3-butadiene, isoprene, and (E)-piperylene are described.Structure analysis of the adducts by NMR spectroscopy is presented.The site selectivity and face diastereoselectivity of the reactions are discussed.

Full text of DOI:10.1021/jo00018a028

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