
Chemistry of Heterocyclic Compounds p. 917 - 920 (1992)
Update date:2022-08-17
Topics:
Doronina, S. O.
Gall', A. A.
Shishkin, G. V.
By heating 1-(2-hydroxyethyl)benzo-1-azonium-4-azabicyclo-<2.2.2>octene halides in anhydrous solvents or via thermolysis, opening of the bicycle occurs with formation of the corresponding N-(2-hydroxyethyl)-N'-(2-haloethyl)-1,2,3,4-tetrahydroquinoxalines.In the presence of base, fission of the hydroxyethyl group principally occurs.
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(1981)