REACTIONS OF METHYLVINYL AND PHENYLVINYL KETONES WITH A TRICYCLIC KETONE DERIVED FROM 2-TETRALONE: CHARACTERISATION OF CRYSTALLINE PRODUCTS BY X-RAY DIFFRACTION.

DOI: 10.1016/S0040-4020(01)87225-2

Source and publish data:

Tetrahedron p. 7487 - 7498 (1993)

Update date:2022-08-25

Topics:

Authors:

Cardin, Christine J.

Carson, Mary S.

Cocker, Wesley

Wilcock, Deborah J.

Shannon, Patrick V. R.

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Article abstract of DOI:10.1016/S0040-4020(01)87225-2

Base catalysed reaction of the tricyclic ketone (6->/<-7) with methylvinyl ketone gave the tetracyclic ketols, 11, 13, 15, 16, and the pentacyclic ketols, 12, 17.With phenylvinyl ketone, the tetracyclic ketol (18) was formed.The stereostructures of the ketols were identified by X-Ray diffraction.

Full text of DOI:10.1016/S0040-4020(01)87225-2

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