A STUDY ON KINETIC C-H-ACIDITY: THE α-EPIMERIZATION OF β-LACTONES

DOI: 10.1016/S0040-4039(01)90488-5

Source and publish data:

Tetrahedron Letters p. 2165 - 2168 (1981)

Update date:2022-08-15

Topics:

Authors:

Mulzer, Johann

Zippel, Matthias

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Article abstract of DOI:10.1016/S0040-4039(01)90488-5

The rate constants of the α-epimerization of the β-lactone 1 show a LFE-correlation with the solvent donicity parameters DN or B; additionally, the kinetic CH-acidity of 1 is unusually high.

Full text of DOI:10.1016/S0040-4039(01)90488-5

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