A STEREOSPECIFIC SYNTHESIS OF CHIRAL 1,3-DISUBSTITUTED BROMOALLENES

DOI: 10.1016/0040-4039(84)80006-4

Source and publish data:

Tetrahedron Letters p. 3055 - 3058 (1984)

Update date:2022-08-11

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Authors:

Corey, E. J.

Boaz, Neil W.

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Article abstract of DOI:10.1016/0040-4039(84)80006-4

Optically active 1,3-disubstituted propargyl alcohols undergo S_Ni' rearrangements with thionyl bromide in the presence of propylene oxide to yield bromoallenes without loss of optical purity.

Full text of DOI:10.1016/0040-4039(84)80006-4

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