A predicative model for certain directed metalations, IV; The dynamic behavior of the organolithio intermediates formed by metalation of p-dimethoxybenzene (p-DMB)

DOI: 10.1016/0040-4039(95)01765-A

Source and publish data:

Tetrahedron Letters p. 8175 - 8178 (1995)

Update date:2022-08-23

Topics:

Authors:

Slocum Slocum

Hayes Hayes

Kline Kline

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Article abstract of DOI:10.1016/0040-4039(95)01765-A

Significant disproportionation between the mono- and 2,5-bis-metalated intermediates resulting from metalation of p-DMB has been observed. The best procedure for the generation of each of these intermediates involves use of an "incremental" amount of TMEDA.¹.

Full text of DOI:10.1016/0040-4039(95)01765-A

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