Regio- and chemo-selectivity of adamantane halogenation by Gif-Barton and metalloporphyrin catalysis and by classical free-radical reactions

DOI: 10.1016/0040-4039(94)80042-1

Source and publish data:

Tetrahedron Letters p. 8033 - 8036 (1994)

Update date:2022-08-16

Topics:

Authors:

Minisci Minisci

Minisci, Francesco

Fontana Fontana

Fontana, Francesca

Zhao Zhao

Zhao, Lihua

Banfi Banfi

Banfi, Stefane

Quici Quici

Quici, Silvio

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Article abstract of DOI:10.1016/0040-4039(94)80042-1

The halogenation of adamantane by CBrCl₃ with Gif-Barton and metalloporphyrin catalysis is compared with classical free-radical halogenations (Br₂, NBS, t-Bu-OCl, R₂NCl) and with the behaviour of simple alkanes (n-hexane, 2,3-dimethylbutane, cyclohexane); the free-radical mechanism is discussed.

Full text of DOI:10.1016/0040-4039(94)80042-1

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