Use of dimethyldioxirane in the preparation of highly reactive compounds: First direct epoxidation of precocenes

DOI: 10.1016/S0040-4039(00)97852-3

Source and publish data:

Tetrahedron Letters p. 5235 - 5236 (1990)

Update date:2022-08-10

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Authors:

Bujons Bujons

Camps Camps

Messeguer

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Article abstract of DOI:10.1016/S0040-4039(00)97852-3

Natural precocenes and related analogues react with dimethyldioxirane to give the corresponding 3,4-epoxy derivatives in very high yields. This procedure constitutes the first direct preparation of these highly reactive compounds.

Full text of DOI:10.1016/S0040-4039(00)97852-3

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