Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 923 - 930 (1988)
Update date:2022-08-11
Topics:
Tagawa, Tomohiko
Imai, Hisao
Mechanistic aspects of the oxidative coupling reaction of methane over an LaAlO3 catalyst (La:Al=1:1) prepared by the mist decomposotion method have been studied, using both contonuous-flow and pulsed-flow techniques.The delayed pulse technique together with temperature-programmed desorption reveal that an adsorbed oxygen species is effective in the formation of the C2 compounds, while a gaseous or weakly adsorbed oxygen species is involved in the combustion reaction.Methane cannot stay on the surface stably.Comparing these results with those obtained using the continuous flow reactor, mechanistic aspects are considered from the viewpoint of oxygen activity.The stability of this catalyst is also discussed.
Shenzhen JYMed Technology Co.,Ltd.
website:http://www.jymedtech.com
Contact:+86-755-26612112
Address:1#8,9/F, Biomedicine innovation Industrial Park, No.14, Jinhui Road, Pingshan Sistrict, Shenzhen, China
Contact:+86-571-86491666
Address:SHI XIANG ROAD
Shanghai Synmedia Chemical Co., Ltd
Contact:+86-21-38681880
Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
Wuhan Soleado Technology Co.,Ltd.
Contact:86-2783341481 18971291927
Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
Hangzhou Kai Peng Biotechnology Co., Ltd.
Contact:86-571-89939007
Address:NO. 499, Wensan West Road, Xihu District, Hangzhou, 310012, China
Doi:10.1016/j.ejmech.2006.09.023
(2007)Doi:10.1016/j.polymer.2016.01.006
(2016)Doi:10.1016/j.jphotochem.2015.11.001
(2016)Doi:10.1016/j.bioorg.2020.103908
(2020)Doi:10.1016/j.catcom.2013.10.009
(2014)Doi:10.1021/acs.joc.7b00486
(2017)
