Journal of Physical Chemistry p. 4703 - 4707 (1985)
Update date:2022-08-24
Topics:
Nava, D. F.
Brobst, W. D.
Stief, L. J.
Absolute rate constants for the reaction of atomic chlorine with hydrogen sulfide, Cl + H2S -> HCl + HS (1) over the temperature range 211 to 353 K, and with episulfide, Cl + C2H4S -> C2H4 + SCl (3) over the temperature range 211 to 298 K, have been measured by the flash photolysis-resonance fluorescence technique.In both systems, the results were independent of substantial variation in reactant concentration, total pressure (Ar), and flash intensity (i.e., initial
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