Preparation of dialkoxyborylbis(bromozincio)methane and its reaction with electrophiles

DOI: 10.1246/cl.1999.747

Source and publish data:

Chemistry Letters p. 747 - 748 (1999)

Update date:2022-08-11

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Authors:

Matsubara, Seijiro

Otake, Yasuyuki

Hashimoto, Yuko

Utimoto, Kiitiro

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Article abstract of DOI:10.1246/cl.1999.747

Dialkoxyborylbis(bromozincio)methane was prepared from dialkoxyboryldibromomethane by the Pb-catalyzed reaction with zinc. The dialkoxyborylbis(bromozincio)methane afforded vinylboranes by TiCl₄-mediated reaction with aldehydes or ketones. The

Full text of DOI:10.1246/cl.1999.747

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