Journal of the Electrochemical Society p. 648 - 650 (1986)
Update date:2022-08-11
Topics:
Stickney
Schardt
Stern
Wieckowski
Hubbard
The authors report on instance in which the energetic driving force for electrosorption, in this case the substantial affinity of tin-oxygen monolayers for the Pt surface, was sufficient to cause spontaneous deposition of monolayer quantities of material upon immersion (of Pt into Sn(II) solutions) at open circuit. Since the electrodeposition of Sn species occurred without flow of current in the external circuit, the deposited species were detected, identified, and quantitated by Auger electron spectroscopy.
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