Zeitschrift fur Anorganische und Allgemeine Chemie p. 304 - 308 (1997)
Update date:2022-08-17
Topics:
Füglein
Hock
Lerch, Martin
Zr2ON2 has been prepared by solid state reaction of ZrO2 with Zr3N4. The crystal structure (Bixbyite-type) was refined using X-ray and neutron powder diffraction methods. The results indicate a nitrogen-oxygen-ordering. As detected by high temperature XRD experiments, Zr2ON2 decomposes at temperatures above 800°C to a fluorite type zirconium oxidenitride phase, nitrogen gas, and ZrN.
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