A study of the selenites of cerium phase states in aqueous medium and thermal properties

DOI: 10.1023/A:1025846901134

Source and publish data:

Journal of Thermal Analysis and Calorimetry p. 859 - 865 (2003)

Update date:2022-08-11

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Authors:

Gospodinov

Stancheva

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Article abstract of DOI:10.1023/A:1025846901134

The solubilities of the systems CeO₂-SeO₂-H ₂O and Ce₂O₃-SeO₂-H₂O were studied at 100°C. The field of crystallization of Ce(SeO ₃)₂ was established in the system CeO₂-SeO ₂-H₂O, and fields of crystallization of Ce ₂(SeO₃)₃ and Ce₂(SeO ₃)₃ H₂SeO₃ were established in the system Ce₂O₃-SeO₂-H₂O. The compound obtained were identified by means of chemical, X-ray and derivatograph analysis. The mechanism of thermal dissociation of Ce(SeO₃)₂, Ce₂(SeO₃)₃ and Ce₂(SeO ₃)₃H₂SeO₃ was studied.

Full text of DOI:10.1023/A:1025846901134

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