Substituent effects on the conformational equilibrium of 1,3,5,7-cis-tetraoxadecalin systems: Force field calculations versus experimental results

DOI: 10.1016/0957-4166(95)00366-W

Source and publish data:

Tetrahedron Asymmetry p. 2767 - 2778 (1995)

Update date:2022-08-17

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Authors:

Santos Santos

Hoffmann

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Article abstract of DOI:10.1016/0957-4166(95)00366-W

Conformer populations of a number of 1,3,5,7-cis-tetraoxadecalins have been studied by ¹H NMR spectroscopy. While the unsubstituted 4 prefers the proximal conformation, all 4,8 disubstituted derivatives 5 preferred the distal conformation. This

Full text of DOI:10.1016/0957-4166(95)00366-W

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