Tetrahedron Letters p. 2305 - 2308 (1982)
Update date:2022-08-11
Topics:
Henning, Rolf
Hoffmann, H. M. R.
Allylic alcohols 3 and 4 have been prepared and activated toward formation of allyl cations, giving 3-methylenebicyclo<3.2.1>oct-6-enes 7 and 9, respectively, in the presence of cyclopentadiene; with furan, not only the products of conventional electrophilic substitution 11 and 13 are formed, but also 3-methylene-8-oxabicyclo<3.2.1>oct-6-enes 12 and 14.
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