Journal of Physical Chemistry p. 3974 - 3976 (1984)
Update date:2022-08-11
Topics:
Cohen, Benyamin
Weiss, Shmuel
Spectra of the ν2 and ν3+ν4 bands of CH3CN in the presence of IBr and in CCl4 solution were measured over a range of temperatures.The spectra could be analyzed to reveal the kinetics of the CH3CN + IBr <*> CH3CN.IBr reaction, in the picosecond range.Association and dissociation rate constants were determined and, from them, activation energies and entropies.
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