Inorganic Chemistry p. 74 - 76 (1973)
Update date:2022-08-16
Topics:
Alexander, John J.
Wojcicki, Andrew
Transition metal carbonyl acyl complexes of the type π-C5H5M(CO)nCOR (M = Fe, n = 2; M, = Mo, n = 3) can be chemically decarbonylated under mild conditions using Rh[P(C6H5)3]3Cl. The products are a mixture of the corresponding alkyl and triphenylphosphine-substituted acyl complexes. The scope and mechanism of this reaction are discussed.
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