
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 841 - 843 (1991)
Update date:2022-08-10
Topics:
Mironov, V. F.
Mavleev, R. A.
Konovalova, I. V.
Ofitserov, E. N.
Pudovik, A. N.
The reactions of phosphites containing electron-withdrawing fluoroalkyl groups with methyl triflate gave tris(fluoroalkoxy)methylphosphonium triflates, which react with alcohols to give either tetrakis(fluoroalkoxy)methylphosphoranes (in the case of fluoroalcohols) or alkylation products - ethers and bis(fluoroalkoxy)methylphosphonates (in the case of unsubstituted alcohols).The structures of the phosphonium salts and phosphoranes were supported by 1H and 31p NMR spectroscopy.
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