Journal of Physical Chemistry p. 5147 - 5150 (1988)
Update date:2022-08-16
Topics:
Orlando, J. J.
Smith, D. R.
This paper describes the time resolved detection of CF3, C2F6, and CO following the infrared multiphoton dissociation of hexafluoroacetone.The primary photolysis mechanism has been estalished as follows: (CF3)2CO -> 2CF3 + CO; 2CF3 -> C2F6.Determination of the CO and C2F6 formed in a single photolysis pulse leads to a measure of an infrared line strength and ν3 band strength for CF3.Quantification of the CF3 in this manner allows a study of its reaction kinetics.The reactions of CF3 with added O2 and NO were found to have third-body rate constants of (2.1 +/- 0.5) * 10-29 and (2.8 +/- 0.7) * 10-29 cm6 molecule-2 s-1, respectively, at room temperature in the presence of 600 mTorr of hexafluoroacetone.
Shenyang Mole pharmaceutical Technology Development Co.,Ltd
Contact:+86-24-31204918/13889278616
Address:No.44, wanliutang road, shenhe District of Shenyang
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.
Contact:+86-186-02659358
Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Contact:021-50278900
Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china
Weifang Dongxing Chitosan Factory
website:http://dxchitosan.lookchem.com/
Contact:13475651157
Address:Weifang city ,shandong province
Cerametek Materials（ShenZhen）Co., Ltd.
Contact:+86-755-2324.2554
Address:A3-#9, YongChuan Street, Suite 501
Doi:10.1021/acsmedchemlett.8b00484
(2019)Doi:10.1021/om0610041
(2007)Doi:10.1021/jo00968a007
(1972)Doi:10.1039/b916882f
(2010)Doi:10.1016/j.ejmech.2018.05.019
(2018)Doi:10.1016/S0040-4039(00)85208-9
(1986)
