
Tetrahedron Letters p. 2703 - 2704 (1989)
Update date:2022-08-11
Topics:
Atkinson, Robert S.
Kelly, Brian J.
Desilylation of aziridine (5) by treatment with cesium fluoride in dry dimethylformamide in the presence of benzaldehyde followed by oxidation with manganese dioxide gives the benzoylaziridine (11) in 80percent yield: in the absence of benzaldehyde, the presumed aziridinyl carbanion intermediate (9) gives the aziridine (7) (58percent).
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