Tetrahedron Letters p. 9435 - 9438 (1998)
Update date:2022-08-17
Topics:
Quiclet-Sire, Beatrice
Zard, Samir Z.
The C-O bond in xanthates derived from carbohydrates can be reductively cleaved by heating in 2-propanol in the presence of equimolar amounts of dilauroyl peroxide, added in small portions; if benzene is used as the solvent, an O- to S- rearrangement of the xanthate occurs.
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