Chemiluminescence and catalysis of decomposition of dimethyldioxirane adsorbed from the gas phase on silipore containing tris(bipyridyl)ruthenium complex Ru(bpy)3Cl2 and 9,10-diphenylanthracene

Article abstract of DOI:10.1007/BF02495595

The kinetics of decomposition of dimethyldioxirane (DMD) adsorbed from the gas phase on the silipore surface was studied by the chemiluminescence (CL) technique. The lower boundary of the CL yield in the reaction of DMD decomposition (4 · 10^-9 Einstein mol^-1) and chemiexcitation yield of methyl acetate (4 · 10^-4) were estimated. Chemiluminescence upon decomposition of DMD on the silipore surface in the presence of activators of CL such as tris(bipyridyl)ruthenium complex Ru(bpy)₃Cl₂ and 9,10-diphenylanthracene was revealed. Ru(bpy)₃Cl₂ activates the luminescence according to chemically induced electron exchange mechanism.