Journal of Organometallic Chemistry p. 45 - 49 (1996)
Update date:2022-08-11
Topics:
Schmid, Michael A.
Alt, Helmut G.
Milius, Wolfgang
The reaction of indenyllithium, IndLi, with CpMCl3 (M = Ti, Zr) or Cp*MCl3 (M = Zr, Hf) leads to complexes of the type (L)(Ind)MCl2 (1: L = Cp, M = Ti; 2: L = Cp, M = Zr; 3: L = Cp*, M = Zr; 4: L = Cp*, M = Hf). In combination with methylaluminoxan (MAO), complexes 1-4 show a high catalytic activity as homogeneous ethylene polymerization catalysts. The ethylene selective catalyst precursor 3 was characterized by an X-ray structure analysis.
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