Journal of the Chemical Society. Perkin transactions I p. 3118 - 3119 (1981)
Update date:2022-08-16
Topics:
Annunziata, Rita
Cinquini, Mauro
Colonna, Stefano
Cozzi, Franco
Both vinyl and β-halogenoethyl sulphilimines can be obtained in optically active form via kinetic resolution in the elimination reaction of the latter promoted by chiral bases, with enantiomeric excesses of up to 73percent; the influence of the resolving agent and of the leaving group on the chiral discrimination has also been examined.
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