Welcome to LookChem.com Sign In|Join Free

Article Doi

The α-Deuterium Secondary Kinetic Isotope Effect upon the Hydrolysis of 2-(p-Nitrophenoxy)tetrahydropyran and its Relationship to Values for the Solvolysis of Secondary Alkyl Arenesulfonates and the Enzyme-catalysed Hydrolysis of Acetals

DOI: 10.1039/c39930000503

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 503 - 504 (1993)

Update date:2022-08-10

Topics:

Authors:

Lee, Won HeuiLee, Won Heui

Maskill, H.Maskill, H.

Manneer, Iain D.Manneer, Iain D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930000503

The α-deuterium secondary kinetic isotope effect for the uncatalysed hydrolysis of 2-(p-nitrophenoxy)tetrahydropyran is 1.17 in water (46 deg C), a result which is very similar to values for the solvolysi of simple secondary alkyl arenesulfonates which proceed with rate-limiting ionization and appreciably higher than results for enzyme-catalysed hydrolysis of other acetals.

View More

Products guided by the article

Product name:Sodium 4-nitrophenoxide

Cas No:824-78-2

824-78-2

Relevant to this article

Hot Product