A new highly regioselective reaction of unprotected sugars for chemical synthesis of methyl-6-D-acyl-D-glycopyranosides by means of chlorophosphoric acid diethyl ester[(C2H5O)2P(:O)Cl] as condensing reagent

Article abstract of DOI:10.1080/00397919608003614

A new methodology which allows the regioselective acylation of no protected methyl-D-glycopyranosides at the primary hydroxy group is described. Thus, a new synthetic procedure is presented to synthesize 6-acyl-methyl-glycopyranosides from unprotected glycopyranosides by means of (EtO)2P:OCl as condensing reagent.

Full text of DOI:10.1080/00397919608003614

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Synthetic Communications:
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A New Highly Regioselective
Reaction of Unprotected
Sugars for Chemical
Synthesis of Methyl-6-D-
acyl-D-glycopyranosides by
Mean of Chlorophosphoric
Acid Diethyl
Ester[(C2H5O)2P(:O)Cl] as
Condensing Reagent
Jie Xia a & Yongzheng Hui a
a State Key Laboratory of Bio-organic and
Natural Products Chemistry , Shanghai Institute
of Organic Chemistry, Chinese Academy of
science , Shanghai, 200032, China
Published online: 21 Aug 2006.
To cite this article: Jie Xia & Yongzheng Hui (1996) A New Highly Regioselective
Reaction of Unprotected Sugars for Chemical Synthesis of Methyl-6-D-acyl-D-
glycopyranosides by Mean of Chlorophosphoric Acid Diethyl Ester[(C2H5O)2P(:O)Cl]
as Condensing Reagent, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 26:2, 269-278, DOI:
10.1080/00397919608003614
To link to this article: http://dx.doi.org/10.1080/00397919608003614

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