
Tetrahedron Letters p. 1875 - 1878 (1992)
Update date:2022-08-29
Topics:
Adam, Waldemar
Ouchi, Akihiko
Argon ion laser-induced photolysis of 1,8-bis(bromomethyl)naphthalene (1) in the laser-jet with benzophenone as sensitizer gave ca. 8% (61% conversion) of acenaphthene (4) through cyclization of the intermediary non-Kekule diradical 1,8-dimethylenenaphthalene; in this two-photon process the first photon (333-nm) consumes 1, whereas the second photon (351 and 364 nm) forms 2, both steps are sensitized by benzophenone.
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