Journal of the Chemical Society. Chemical communications p. 1139 - 1141 (1986)
Update date:2022-08-16
Topics:
Seo, Shujiro
Sankawa, Ushio
Seto, Haruo
Uomori, Atsuko
Yoshimura, Yohko
et al.
The fate of the hydrogen atoms originating from <2-(13)C,2-(2)H3>acetate was investigated in the biosynthesis of sitosterol (5) in cultured cells of Rabdosia japonica Hara and ergosterol (6) in yeast and the 1,2-hydride shifts, 20-H from C-17 and 17-H from C-13, were verified.
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