Bicyclo[2.2.1]heptan-1-ylcarbene can ring expand

DOI: 10.1016/S0040-4039(98)00840-5

Source and publish data:

Tetrahedron Letters p. 4433 - 4436 (1998)

Update date:2022-08-30

Topics:

Authors:

Ruck, Rebecca T.

Jones Jr., Maitland

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Article abstract of DOI:10.1016/S0040-4039(98)00840-5

Generation of bicyclo[2.2.1]heptan-1-ylcarbene from a hydrocarbon precursor avoids the problems that attend generation from nitrogenous molecules and allows the determination that such carbenes can ring expand to bridgehead alkenes.

Full text of DOI:10.1016/S0040-4039(98)00840-5

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