Direct Structural Determination of the Short-lived Intermediate Formed in the Dynamic Incorporation of a Copper(II) Ion into a Mercury(II) Porphyrin by the Stopped-flow EXAFS Method

DOI: 10.1039/c39940001023

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1023 - 1026 (1994)

Update date:2022-08-17

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Authors:

Ohtaki, Hitoshi

Inada, Yasuhiro

Funahashi, Shigenobu

Tabata, Masaaki

Ozutsumi, Kazuhiko

Nakajima, Kiyohiko

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Article abstract of DOI:10.1039/c39940001023

Structure parameters around the Cu^II ion in a reaction intermediate formed in the course of Cu^II ion incorporation into an Hg^II porphyrin were directly determined using a new stopped-flow EXAFS apparatus, and elongation of the Cu-N bond in the unstable heterodinuclear porphyrin intermediate was observed.

Full text of DOI:10.1039/c39940001023

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