Tetrahedron Letters p. 1263 - 1264 (1988)
Update date:2022-08-31
Topics:
Fitjer, Lutz
Majewski, Marita
Kanschik, Andreas
The dispiro<3.0.4.2>undecanes 2 and 6 undergo cascade rearrangements yielding the <3.3.3>propellanes 3 and 7, respectively.The rearrangement of 6 proceeds regiospecifically and renders 9 a promising candidate for a direct conversion to (+/-)modhephene 10.
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Doi:10.1021/acs.orglett.8b02668
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