REDUCTIVE CLEAVAGES OF CHIRAL ACETALS USING LEWIS ACID-HYDRIDE SYSTEM

DOI: 10.1016/S0040-4039(00)84156-8

Source and publish data:

Tetrahedron Letters p. 987 - 990 (1986)

Update date:2022-08-24

Topics:

Authors:

Mori, Atsunori

Ishihara, Kazuaki

Yamamoto, Hisashi

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Article abstract of DOI:10.1016/S0040-4039(00)84156-8

The reaction of the acetal, derived from (2R,4R)-2,4-pentanediol and a ketone, with Lewis acid-hydride system produces the reductively cleaved product under the mild conditions with high stereoselectivity.

Full text of DOI:10.1016/S0040-4039(00)84156-8

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