Synthesis and reactions of the tungsten nonheteroatom-stabilised carbene anion -

DOI: 10.1016/0022-328X(89)87365-6

Source and publish data:

Journal of Organometallic Chemistry p. C18 - C24 (1989)

Update date:2022-08-30

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Authors:

Winter, Mark J.

Woodward, Simon

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Article abstract of DOI:10.1016/0022-328X(89)87365-6

Treatment of CpW(SnPh3)(CO)2(=CHPh) with I2 gives the nonheteroatom-stabilised carbene complex (CpWI(CO)2(=CHPh), whose reduction by NaC10H8 gives the nonheteroatom stabilised carbene anion ^-, the first member of a new class of

Full text of DOI:10.1016/0022-328X(89)87365-6

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