Metallation reactions of diphosphiranes: new access to ?- and ?-diphosphaallyl complexes

DOI: 10.1016/0022-328X(93)80330-E

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Journal of Organometallic Chemistry p. 77 - 84 (1993)

Update date:2022-08-17

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Authors:

El-Ouatib, Rachida

Ballivet-Tkatchenko, Danielle

Etemad-Moghadam, Guita

Koenig, Max

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Article abstract of DOI:10.1016/0022-328X(93)80330-E

The metallation reactions of the functionalized diphosphiranes 1a,b, with the anionic metal transition complexes Na<(Cp)nM(CO)m> (M = Mo, W, or Co) afford ?- or ?-diphosphaallyl complexes depending on the substituents of the intracyclic carbon atom.The sa

Full text of DOI:10.1016/0022-328X(93)80330-E

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