
Tetrahedron p. 3111 - 3122 (1990)
Update date:2022-08-25
Topics:
Barton, Derek H. R.
Khamsi, Jamal
Ozbalik, Nubar
Reibenspies, Joe
The Pd(0) induced coupling of phenyl groups in triphenylantimony to afford diphenyl and Sb(0) has been studied in a search for possible intermediates. Two complexes containing antimony and palladium have been isolated.Their structures have been determined by x-ray crystallography.Complex 1 is made up of triphenylantimony coordinated to palladium diacetate.It affords diphenyl nearly quantitatively on pyrolysis.Complex 2 contains a phenyl-palladium ?-bond as well as two coordinated triphenylantimony residues.
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(1989)