ESR spectra and electronic structure of the MoO3+ complex with the dithiocarbamate ligand

Article abstract of DOI:10.1007/BF02494849

ESR spectra of liquid and frozen benzene solutions of isotope-enriched ^95,97,98Mo^VO(dtc)₃ complexes ([xMo] > 95%, dtc is the N,N-diethyl dithiocarbamate ligand) and their solid solutions in a matrix of tetraethylthiuram disulfide were studied in the X-range. Comparison of the experimental and calculated parameters of the ESR spectra shows that the axial symmetry of the magnetic tensors does not contradict the low symmetry of the complex, in which the "ylic" oxygen and five of six S atoms in three dithiocarbamate ligands form the coordination sphere of the metal.