Application of Kinetic, Asymmetric Selection to the Breaking of Molecular Symmetry

DOI: 10.1021/jo00216a053

Source and publish data:

Journal of Organic Chemistry p. 3025 - 3026 (1985)

Update date:2022-08-15

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Authors:

Whitesell, James K.

Allen, Diane E.

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Article abstract of DOI:10.1021/jo00216a053

Reaction of the chiral glyoxylate 1 with 1 equiv of diene 2 in dichloromethane at -78 deg C in the presence of a stoichiometric amount of stannic chloride afforded the ene adduct 3 in 74percent chemical yield after chromatographic purification.The combina

Full text of DOI:10.1021/jo00216a053

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