Enantioselective total synthesis of (+)-isoboonein

DOI: 10.1248/cpb.46.1451

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1451 - 1453 (1998)

Update date:2022-08-30

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Authors:

Tada, Masahiro

Inoue, Sayako

Miki, Takao

Onogi, Shin-Ichi

Kaminaga, Jun-Ichi

Hiraoka, Junko

Kitano, Yoshikazu

Chiba, Kazuhiro

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Article abstract of DOI:10.1248/cpb.46.1451

Enantioselective total synthesis of (+)-isoboonein, an iridoid lactone, was accomplished from (-)-dimenthyl bicyclo[2.2.1]hept-5-ene-2,3- dicarboxylate, which was synthesized by diastereoselective Diels-Alder reaction of dimenthyl fumarate with cyclopentadiene.

Full text of DOI:10.1248/cpb.46.1451

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