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Germanium chloride(GeCl2) (6CI,8CI,9CI)

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Name

Germanium chloride(GeCl2) (6CI,8CI,9CI)

EINECS N/A
CAS No. 10060-11-4 Density g/cm3
PSA 18.46000 LogP 1.25640
Solubility decomposes in H2O; soluble ether, benzene; insolublealcohol and chloroform [HAW93] [MER06] Melting Point 110-165°C (dec.)
Formula Cl2Ge Boiling Point °Cat760mmHg
Molecular Weight 143.496 Flash Point °C
Transport Information N/A Appearance N/A
Safety
Risk Statements 34
Safety Statements 26-36/37/39
RIDADR 1759
TSCA No
HazardClass 8
PackingGroup III
Risk Codes 34
Molecular Structure Molecular Structure of 10060-11-4 (GERMANIUM DICHLORIDE-DIOXANE COMPLEX) Hazard Symbols N/A
Synonyms

Dichlorogermylene;Germanium dichloride; Germanium(2+) chloride

Article Data 4

Germanium chloride(GeCl2) (6CI,8CI,9CI) Synthetic route

623-73-4

diazoacetic acid ethyl ester

1188-14-3

Triethylgerman

10038-98-9

germaniumtetrachloride

100-58-3

phenylmagnesium bromide

A

10060-11-4

germanium dichloride

B

2817-41-6

triethyl(phenyl)germane

C

1048-05-1

tetraphenylgermane

Conditions
ConditionsYield
In pentane byproducts: N2; 1 equiv of diazoester adding to a soln. of equimolar mixt. of Ge derivs., allowing to stand for 48 h at 20°C, orange-red oil decanting, PhMgBr adding to a supernatant; identified as adduct with ClCH2OMe;A 57%
B n/a
C n/a
7440-56-4

germanium

7790-99-0

Iodine monochloride

A

21110-21-4

germanium monochloride

B

10060-11-4

germanium dichloride

Conditions
ConditionsYield
In gas Kinetics; metals were vaporized in a high temperature beam and the vapor were collimated upon entering a separatly pumped chamber filled with halogen; chemiluminescence spectroscopy;

germanium(II) sulfide

lead(II) chloride

10060-11-4

germanium dichloride

Conditions
ConditionsYield
excess of GeS;
7440-56-4

germanium

10038-98-9

germaniumtetrachloride

10060-11-4

germanium dichloride

Conditions
ConditionsYield
350-400°C;
13465-77-5

hexachlorodisilane

10038-98-9

germaniumtetrachloride

10060-11-4

germanium dichloride

Conditions
ConditionsYield
In neat (no solvent, gas phase) at 550°C; detn. by chemical trapping;
1184-65-2

germanium hydride trichloride

10060-11-4

germanium dichloride

Conditions
ConditionsYield
byproducts: HCl; thermal decompn.;
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