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10544-72-6

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Basic Information
CAS No.: 10544-72-6
Name: Dinitrogen tetroxide
Molecular Structure:
Molecular Structure of 10544-72-6 (Dinitrogen tetroxide)
Formula: N2O4
Molecular Weight: 92.011
Synonyms: Dinitrogentetraoxide; Dinitrogen tetroxide; Nitrogen tetraoxide; Nitrogen tetroxide
EINECS: 234-126-4
Density: 2.62 g/mL at 25 °C(lit.)
Melting Point: ?11 °C(lit.)
Boiling Point: 21 °C(lit.)
Flash Point: °C
Solubility: reacts with water
Appearance: Transparent gas
Hazard Symbols: VeryT+
Risk Codes: 26-34
Safety: A poison. Moderately toxic by inhalation. When heated to decomposition it emits toxic fumes of NOx. See also NITROGEN MONOXIDE, mixed with NITROGEN TETROXIDE.
Transport Information: UN 1067 2
PSA: 91.64000
LogP: 0.50120
Synthetic route
626-35-7

nitroacetic acid ethyl ester

64-17-5

ethanol

sodium nitrite

sodium nitrite

A

10544-72-6

dinitrogen tetraoxide

B

15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

C

nitrogen

nitrogen

110-46-3

isopentyl nitrite

A

10544-72-6

dinitrogen tetraoxide

B

15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

C

590-86-3

isovaleraldehyde

D

nitrogen

nitrogen

Conditions
ConditionsYield
at 50 - 80℃; Kinetics; Pyrolysis;
7664-93-9

sulfuric acid

10544-72-6

dinitrogen tetraoxide

Conditions
ConditionsYield
at 85℃; Rate constant;
114959-87-4

(+/-)-erythro-2,3-dibromo-butyrohydroxamic acid

ammonium hydroxide

A

625-37-6

crotonamide

B

10544-72-6

dinitrogen tetraoxide

7647-01-0

hydrogenchloride

ethylnitrolic acid

A

10544-72-6

dinitrogen tetraoxide

B

64-19-7

acetic acid

Conditions
ConditionsYield
at 20 - 40℃; Rate constant;

ethylnitrolic acid

7664-93-9

sulfuric acid

A

10544-72-6

dinitrogen tetraoxide

B

64-19-7

acetic acid

Conditions
ConditionsYield
at 39.5℃; Rate constant;
4312-87-2

formohydroxamic acid

7664-93-9

sulfuric acid

sodium nitrite

sodium nitrite

A

64-18-6

formic acid

B

10544-72-6

dinitrogen tetraoxide

C

15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

D

nitrogen

nitrogen

60-29-7

diethyl ether

5156-40-1

cyclohexyl nitrite

lithium alanate

lithium alanate

A

7664-41-7

ammonia

B

10544-72-6

dinitrogen tetraoxide

C

108-93-0

cyclohexanol

D

hydrogen

hydrogen

Conditions
ConditionsYield
anschliessend Behandeln mit Wasser;
60-29-7

diethyl ether

2108-66-9

cyclohexyl nitrate

lithium alanate

lithium alanate

A

7664-41-7

ammonia

B

10544-72-6

dinitrogen tetraoxide

C

108-93-0

cyclohexanol

D

hydrogen

hydrogen

Conditions
ConditionsYield
anschliessend Behandeln mit Wasser;
623-11-0

1-methyl-4-nitrosobenzene

495-18-1

Benzohydroxamic acid

potassium permanganate

potassium permanganate

A

10544-72-6

dinitrogen tetraoxide

B

nitrogen

nitrogen

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  • NITROGEN DIOXIDE CAS NO.10544-72-6

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    10544-72-6

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    NITROGEN DIOXIDE CAS NO.10544-72-6

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Chemistry

Synonyms: Distickstofftetroxid;N2O4;nitrogentetroxide,liquid;Nitrogen oxide (N2O4);nitrogenoxide(n2o4);nitrogentetraoxide;
MF: N2O4
MW: 92.01
mp:-11℃(lit.)
bp:21℃(lit.)
density:2.62 g/mL at 25 ℃(lit.)
vapor pressure:14.33 psi (20℃)
vapor density:1.58 (21℃, vsair)
EINECS: 233-272-6

Uses

It mainly  used as a rocket propellant。

Toxicity Data With Reference

1.   

ihl-rbt LC50:315 ppm/15M

   AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),457.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A poison. Moderately toxic by inhalation. When heated to decomposition it emits toxic fumes of NOx. See also NITROGEN MONOXIDE, mixed with NITROGEN TETROXIDE.
WGK Germany:1
Hazard Codes:T+
RTECS:QX1575000
RIDADR :UN 1067 2.3
Risk Statements:26-34
Safety Statements:9-26-28-36/37/39-45

Standards and Recommendations

DOT Classification:  2.3; Label: Poison Gas, Oxidizer