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Cas Database

Name	NITROGEN TETROXIDE	EINECS	234-126-4
CAS No.	10544-72-6	Density	2.62 g/mL at 25 °C(lit.)
PSA	91.64000	LogP	0.50120
Solubility	reacts with water	Melting Point	?11 °C(lit.)
Formula	N2O4	Boiling Point	21 °C(lit.)
Molecular Weight	92.011	Flash Point	°C
Transport Information	UN 1067 2	Appearance	Transparent gas
Safety	A poison. Moderately toxic by inhalation. When heated to decomposition it emits toxic fumes of NO_x. See also NITROGEN MONOXIDE, mixed with NITROGEN TETROXIDE.	Risk Codes	26-34
Molecular Structure		Hazard Symbols	T+
Synonyms	Dinitrogentetraoxide; Dinitrogen tetroxide; Nitrogen tetraoxide; Nitrogen tetroxide	Article Data	183

NITROGEN TETROXIDE Synthetic route

: 626-35-7
nitroacetic acid ethyl ester

: 64-17-5
ethanol

sodium nitrite: sodium nitrite

A: 10544-72-6
dinitrogen tetraoxide

B: 15719-64-9, 15719-76-3, 97762-63-5
methylammonium carbonate

C nitrogen: nitrogen

...Expand

: 110-46-3
isopentyl nitrite

A: 10544-72-6
dinitrogen tetraoxide

B: 15719-64-9, 15719-76-3, 97762-63-5
methylammonium carbonate

C: 590-86-3
isovaleraldehyde

D nitrogen: nitrogen

Conditions

Conditions	Yield
at 50 - 80℃; Kinetics; Pyrolysis;

: 14168-44-6
MEDINA

: 7664-93-9
sulfuric acid

: 10544-72-6
dinitrogen tetraoxide

Conditions

Conditions	Yield
at 85℃; Rate constant;

: 114959-87-4
(+/-)-erythro-2,3-dibromo-butyrohydroxamic acid

: ammonium hydroxide

A: 625-37-6
crotonamide

B: 10544-72-6
dinitrogen tetraoxide

: 7647-01-0
hydrogenchloride

: ethylnitrolic acid

A: 10544-72-6
dinitrogen tetraoxide

B: 64-19-7
acetic acid

Conditions

Conditions	Yield
at 20 - 40℃; Rate constant;

: ethylnitrolic acid

: 7664-93-9
sulfuric acid

A: 10544-72-6
dinitrogen tetraoxide

B: 64-19-7
acetic acid

Conditions

Conditions	Yield
at 39.5℃; Rate constant;

: 4312-87-2
formohydroxamic acid

: 7664-93-9
sulfuric acid

sodium nitrite: sodium nitrite

A: 64-18-6
formic acid

B: 10544-72-6
dinitrogen tetraoxide

C: 15719-64-9, 15719-76-3, 97762-63-5
methylammonium carbonate

D nitrogen: nitrogen

...Expand

: 60-29-7
diethyl ether

: 5156-40-1
cyclohexyl nitrite

lithium alanate: lithium alanate

A: 7664-41-7
ammonia

B: 10544-72-6
dinitrogen tetraoxide

C: 108-93-0
cyclohexanol

D hydrogen: hydrogen

Conditions

Conditions	Yield
anschliessend Behandeln mit Wasser;

...Expand

: 60-29-7
diethyl ether

: 2108-66-9
cyclohexyl nitrate

lithium alanate: lithium alanate

A: 7664-41-7
ammonia

B: 10544-72-6
dinitrogen tetraoxide

C: 108-93-0
cyclohexanol

D hydrogen: hydrogen

Conditions

Conditions	Yield
anschliessend Behandeln mit Wasser;

...Expand

: 623-11-0
1-methyl-4-nitrosobenzene

: 495-18-1
Benzohydroxamic acid

potassium permanganate: potassium permanganate

A: 10544-72-6
dinitrogen tetraoxide

B nitrogen: nitrogen

NITROGEN TETROXIDE Chemical Properties

Synonyms: Distickstofftetroxid;N2O4;nitrogentetroxide,liquid;Nitrogen oxide (N2O4);nitrogenoxide(n2o4);nitrogentetraoxide;
MF: N₂O₄
MW: 92.01
mp：-11℃(lit.)
bp：21℃(lit.)
density：2.62 g/mL at 25 ℃(lit.)
vapor pressure：14.33 psi (20℃)
vapor density：1.58 (21℃, vsair)
EINECS: 233-272-6

NITROGEN TETROXIDE Uses

It mainly used as a rocket propellant。

NITROGEN TETROXIDE Toxicity Data With Reference

ihl-rbt LC50:315 ppm/15M

AIHAAP American Industrial Hygiene Association Journal. 23 (1962),457.

NITROGEN TETROXIDE Consensus Reports

Reported in EPA TSCA Inventory.

NITROGEN TETROXIDE Safety Profile

A poison. Moderately toxic by inhalation. When heated to decomposition it emits toxic fumes of NO_x. See also NITROGEN MONOXIDE, mixed with NITROGEN TETROXIDE.
WGK Germany：1
Hazard Codes：T+
RTECS：QX1575000
RIDADR ：UN 1067 2.3
Risk Statements：26-34
Safety Statements：9-26-28-36/37/39-45

NITROGEN TETROXIDE Standards and Recommendations

DOT Classification: 2.3; Label: Poison Gas, Oxidizer

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