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Nickel chloride

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Name

Nickel chloride

EINECS 231-743-0
CAS No. 7718-54-9 Density 3.55 g/cm3
PSA 0.00000 LogP 1.37900
Solubility slightly soluble in water Melting Point 1001 °C
Formula NiCl2 Boiling Point Sublimes at 973oC; deliquesces
Molecular Weight 129.596 Flash Point N/A
Transport Information UN 3288 6.1/PG 3 Appearance Golden yellow crystalline powder
Safety 53-26-36/37-45-61-37-29-24 Risk Codes 45-25-36/38-43-50-50/53-22-52/53
Molecular Structure Molecular Structure of 7718-54-9 (Nickel chloride) Hazard Symbols ToxicT,DangerousN
Synonyms

NSC254532;Nickel dichloride;Nickel dichloride (NiCl2);Nickel(2+) chloride;Nickel(II) chloride;Nickelous chloride;Nickelchloride (NiCl2);

Article Data 4

Nickel chloride Synthetic route

7440-02-0

nickel

silver(I) chloride

7718-54-9

nickel(II) chloride

Conditions
ConditionsYield
In neat (no solvent, solid phase) mixt. of metal (tenfold excess) and AgCl heated in Ar (400 Torr) until react. was complete; cooled, evacuated, co-condensed with solid matrix (N2 or Ar);
7647-01-0

hydrogenchloride

7440-02-0

nickel

7718-54-9

nickel(II) chloride

Conditions
ConditionsYield
In water Dissoln. of Ni wire in aq. HCl at about 50°C using a piece of Pt in contact with the Ni (acting as cathode for better soln. of Ni).; Placement of NiCl2 in a quartz boat, vaporisation by heating to about 600°C, seeding of vapor in about 4 atm of Ar, expanding through nozzle (250μm hole).;
In neat (no solvent) isolation in N2 or CH4 solid matrix;
802907-39-7

7-((R)-2-hydroxymethyl-6-oxo-piperidin-1-yl)-hept-5-ynoic acid methyl ester

7718-54-9

nickel(II) chloride

7-((R)-2-hydroxymethyl-6-oxo-piperidin-1-yl)-hept-5-enoic acid methyl ester

Conditions
ConditionsYield
With sodium borohydrid In ethanol; ethylenediamine16.7 mg (38%)
623-03-0

4-Cyanochlorobenzene

258885-52-8

4-(5-bromo-2-methylbenzyl)-5-methoxy-2-methyl-2,4-dihydro-3H,1-2,4-triazol-3-one

7718-54-9

nickel(II) chloride

258885-71-1

4-{5-(4-cyanophenyl)-2-methylbenzyl}-5-methoxy-2-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one

Conditions
ConditionsYield
With hydrogenchloride; sodium hydrogencarbonate; triphenylphosphine In pyridine; water; ethyl acetate
[(4-methoxybenzenesulfonyl)-2-oxo-athyl)-amino]acetic acid t-butyl ester

[(4-methoxybenzenesulfonyl)-2-oxo-athyl)-amino]acetic acid t-butyl ester

42599-24-6

E-styryl iodide

10049-05-5

chromium (II) chloride

7718-54-9

nickel(II) chloride

(+)-(E)-[(2-hydroxy-4-phenyl-but-3-enyl)-(4-methoxybenzenesulphonyl)-amino]-acetic acid t-butyl ester

Conditions
ConditionsYield
In N-methyl-acetamide
593-60-2

Vinyl bromide

154-87-0

thiamine diphosphate

7718-54-9

nickel(II) chloride

138526-69-9

3,4,5-trifluoro-1-bromobenzene

3,4,5-Trifluorovinylbenzene

Conditions
ConditionsYield
With n-butyllithium; zinc dibromide In tetrahydrofuran
620-73-5

phenyl chloroacetate

106-43-4

para-chlorotoluene

7718-54-9

nickel(II) chloride

127783-74-8

4-acetoxy-4’-methylbiphenyl

Conditions
ConditionsYield
With sodium iodide; zinc In N-methyl-acetamide; chloroform
697802-45-2

7-[2-oxo-6-((E)-3-oxo-oct-1-enyl)-piperidin-1-yl]-hept-5-ynoic acid methyl ester

7718-54-9

nickel(II) chloride

697802-47-4

(Z)-7-[2-oxo-6-((E)-3-oxo-oct-1-enyl)-piperidin-1-yl]-hept-5-enoic acid methyl ester

Conditions
ConditionsYield
With sodium borohydrid In ethanol; ethyl acetate; ethylenediamine65 mg (43%)
697802-67-8

7-[2-oxo-6-((E)-3-oxo-4-phenyl-but-1-enyl)-piperidin-1-yl]-hept-5-ynoic acid methyl ester

7718-54-9

nickel(II) chloride

697802-69-0

(Z)-7-[2-oxo-6-((E)-3-oxo-4-phenyl-but-1-enyl)-piperidin-1-yl]-hept-5-enoic acid methyl ester

Conditions
ConditionsYield
With sodium borohydrid In ethanol; ethylenediamine28 mg (70%)
With sodium borohydrid In ethanol; ethylenediamine28 mg (70%)

Nickel chloride Chemical Properties

IUPAC Name: Dichloronickel
Synonyms: Nickel (II) chloride ; Nickel (II) chloride (1:2) ; Nickel(2+) dichloride ; Nickel(II) chloride (1:2)
Product Categories: Inorganics;Catalysis and Inorganic Chemistry;Chemical Synthesis;Nickel Salts;NickelMetal and Ceramic Science;Salts;Crystal Grade Inorganics;Metal and Ceramic Science
Molecular Formula of Nickel chloride (CAS NO.7718-54-9) : NiCl2
Molecular Weight of Nickel chloride (CAS NO.7718-54-9) : 129.60
Molecular Structure of Nickel chloride (CAS NO.7718-54-9) :
CAS NO: 7718-54-9
EINECS : 231-743-0
Mol File: 7718-54-9.mol
Melting point: 1001 °C
Boiling Point: 987°C
Density : 3.55 g/mL at 25 °C(lit.)
Solubility: H2O: soluble
Water Solubility: slightly soluble
Sensitive: Hygroscopic
Merck : 14,6505
Stability: Stable. Incompatible with peroxides.
Appearance:Golden yellow crystalline powder

Nickel chloride Uses

 Nickel chloride (CAS NO.7718-54-9) is used for nickel, manufacture of sympathetic ink and Ammonia absorber.

Nickel chloride Production

Preparation Products Nickel(II) chloride hexahydrate-->(4-(4-[BIS(4-FLUOROPHENYL)METHYL]PIPERAZIN-1-YL)PHENYL)METHANOL-->Nickel(II) nitrate hexahydrate-->(1,3-DIMETHYL-1H-PYRAZOL-5-YL)METHYLAMINE-->2-(1,3-Dimethyl-1H-pyrazol-5-yl)ethanamine ,97%-->(1,5-DIMETHYL-1H-PYRAZOL-3-YL)METHYLAMINE-->Nickel dibutyldithiocarbamate
Raw materials Hydrochloric acid-->Sulfuric acid -->Nitric acid-->Sodium carbonate-->Nickel-->Nickel sulfate -->Nickel carbonate

Nickel chloride Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 11mg/kg (11mg/kg)   Toxicology. Vol. 64, Pg. 19, 1990.
mouse LD50 intravenous 20mg/kg (20mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
mouse LD50 oral 369mg/kg (369mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rabbit LD50 intramuscular 27mg/kg (27mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 87, Pg. 119, 1946.
rat LD50 intraperitoneal 20597ug/kg (20.597mg/kg)   Toxicology. Vol. 35, Pg. 47, 1985.
rat LD50 intravenous 68100ug/kg (68.1mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rat LD50 oral 681mg/kg (681mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.

Nickel chloride Safety Profile

Hazard Codes ToxicTDangerousN,IrritantXi
Risk Statements 45-25-36/38-43-50/53-22-52
R22:Harmful if swallowed. 
R25 :Toxic if swallowed. 
R45:May cause cancer. 
R43:May cause sensitization by skin contact.
R36/38:Irritating to eyes and skin. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R52:Harmful to aquatic organisms.
Safety Statements 53-26-36/37-45-61-29-24 
S53:Avoid exposure - obtain special instructions before use. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37:Wear suitable protective clothing and gloves. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. 
S29:Do not empty into drains. 
S24:Avoid contact with skin.
RIDADR UN 3288 6.1/PG 3
WGK Germany 3
RTECS QR6475000
F 3
HazardClass 6.1(b)
PackingGroup III

Nickel chloride Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dangerous fire hazard in the form of dust when exposed to heat or flame.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage: Store in a cool, dry place. Store in a tightly closed container. Store under nitrogen.

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