(4-Methoxyphenyl)-N,N-dimethylmethaniminium iodide

Base Information

• Chemical Name: (4-Methoxyphenyl)-N,N-dimethylmethaniminium iodide
• CAS No.: 79865-85-3
• Molecular Formula: C10H14NO.I
• Molecular Weight: 291.132
• DSSTox Substance ID: DTXSID60507762
• Mol file: 79865-85-3.mol

Synonyms:79865-85-3;(4-Methoxyphenyl)-N,N-dimethylmethaniminium iodide;DTXSID60507762

Chemical Property of (4-Methoxyphenyl)-N,N-dimethylmethaniminium iodide

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 291.01201
• Heavy Atom Count: 13
• Complexity: 153

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[N+](=CC1=CC=C(C=C1)OC)C.[I-]

Technology Process of (4-Methoxyphenyl)-N,N-dimethylmethaniminium iodide

There total 3 articles about (4-Methoxyphenyl)-N,N-dimethylmethaniminium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-methoxybenzyl-N-methylimine (13114-23-3) + methyl iodide (74-88-4) → p-methoxybenzylidenedimethylimmonium iodide (79865-85-3)

Guidance literature:

for 10h; Ambient temperature;

Reference yield:

chloro-trimethyl-silane (75-77-4) + N,N-Dimethyltrimethylsilylamine (2083-91-2) + 4-methoxy-benzaldehyde (123-11-5) → Hexamethyldisiloxane (107-46-0) + p-methoxybenzylidenedimethylimmonium iodide (79865-85-3)

Guidance literature:

With sodium iodide; In acetonitrile; for 0.5h; Ambient temperature;

DOI:10.1055/s-1997-946

Reference yield:

4-methoxy-benzaldehyde (123-11-5) → p-methoxybenzylidenedimethylimmonium iodide (79865-85-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 80 percent / H₂O / 10 h / Ambient temperature

2: 90 percent / 10 h / Ambient temperature

In water;

upstream raw materials:

4-methoxybenzyl-N-methylimine

methyl iodide

chloro-trimethyl-silane

N,N-Dimethyltrimethylsilylamine

Downstream raw materials:

(4-dimethylamino-benzylidene)-dimethyl-ammonium; iodide

4-dimethylamino-benzaldehyde

4-butylamino-benzaldehyde

4-(ethylamino)benzaldehyde