1,1,2-Trimethoxyethane

Base Information

• Chemical Name: 1,1,2-Trimethoxyethane
• CAS No.: 24332-20-5
• Molecular Formula: C5H12 O3
• Molecular Weight: 120.148
• Hs Code.: 2909199090
• European Community (EC) Number: 246-175-9
• UNII: 682PCN62W8
• DSSTox Substance ID: DTXSID50179073
• Nikkaji Number: J121.205B
• Wikidata: Q63392750
• Mol file: 24332-20-5.mol

Synonyms:1,1,2-Trimethoxyethane;24332-20-5;Methoxyacetaldehyde dimethyl acetal;Ethane, 1,1,2-trimethoxy-;2-Methoxyacetaldehyde dimethyl acetal;682PCN62W8;EINECS 246-175-9;MFCD00008486;1,1,2-trimethoxy-ethane;SCHEMBL142415;UNII-682PCN62W8;methoxyacetaldehyde dimetylacetal;DTXSID50179073;1,1,2-TRIS(METHOXY)ETHANE;AKOS006221653;BS-16763;SY050730;AM20080585;CS-0150200;FT-0605991;T0831;EN300-88702;A817232;J-015448;Methoxyacetaldehyde dimethyl acetal, >=98.0% (GC);Q63392750;1-IODO-4-(TRIFLUOROMETHYL)OCTAFLUOROPENT-2-ENE97

Chemical Property of 1,1,2-Trimethoxyethane

Chemical Property:

• Refractive Index: n20/D 1.392(lit.)
• Boiling Point: 56-59 ºC (56 mmHg)
• Flash Point: 23 ºC
• PSA: 27.69000
• Density: 0.932
• LogP: 0.25170
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• XLogP3: -0.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 120.078644241
• Heavy Atom Count: 8
• Complexity: 42.9

Purity/Quality:

98% ^*data from raw suppliers

Methoxyacetaldehyde Dimethyl Acetal ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: COCC(OC)OC

Technology Process of 1,1,2-Trimethoxyethane

There total 10 articles about 1,1,2-Trimethoxyethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

methanol (67-56-1) + 1,2-dimethoxyethane (110-71-4) → methoxyacetaldehyde dimethylacetal (24332-20-5)

Guidance literature:

With tris (2,4-dibromophenyl)amine; sodium methylate; lithium perchlorate; at 40 ℃; electrochem. oxidation;

DOI:10.1016/S0040-4020(01)87786-3

Reference yield:

methanol (67-56-1) + cellulose (9004-34-6) → 5-(methoxymethyl)-2-furaldehyde (1917-64-2) + methyl levulinate (13984-50-4) + methoxyacetaldehyde dimethylacetal (24332-20-5)

Guidance literature:

With Mesoporous niobium-based phosphate Al-NbP-pH₂ (obtained at pH=2); In water; at 180 ℃; for 25h; under 6000.6 Torr; Reagent/catalyst; Autoclave; Inert atmosphere; Green chemistry;

DOI:10.1039/c5gc00440c

Reference yield:

Dimethoxymethane (109-87-5) → methoxyacetaldehyde dimethylacetal (24332-20-5)

Guidance literature:

With methanol; cobalt catalyst; hydrogen; at 160 - 170 ℃; under 441305 Torr;

upstream raw materials:

1-bromo-2,2-dimethoxyethane

sodium methylate

methanol

methoxyethene

Downstream raw materials:

1,2-Dimethoxyethene

3-Dimethylamino-2-methoxyacrolein

(Z)-1,2-Dimethoxyethylen

1-(3'-trifluoromethyl-phenyl)-2-methoxymethyl-1,2-dihydro-3,1-benzoxazin-4-one