Neodymium triiodide

Base Information

• Chemical Name: Neodymium triiodide
• CAS No.: 13813-24-6
• Molecular Formula: I3Nd
• Molecular Weight: 524.954
• European Community (EC) Number: 237-467-7
• DSSTox Substance ID: DTXSID0065642
• Wikipedia: Neodymium(III) iodide
• Wikidata: Q1452045
• Mol file: 13813-24-6.mol

Synonyms:Neodymium(III) iodide;Neodymium triiodide;13813-24-6;Neodymium iodide;triiodoneodymium;Neodymium iodide (NdI3);NdI3;MFCD00016248;DTXSID0065642;Neodymium(III) iodide, anhydrous;EINECS 237-467-7;CS-0111907;Neodymium(III) iodide, anhydrous, powder, 99.9%;Q1452045

Chemical Property of Neodymium triiodide

Chemical Property:

• Melting Point: 775°C
• PSA: 0.00000
• Density: 5.850
• LogP: 2.65710
• Sensitive.: Moisture & Light Sensitive
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 522.6211
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Neodymium(III) iodide, anhydrous (99.9%-Nd) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 42/43-63
• Safety Statements: 22-36/37-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Rare Earth Metals
• Canonical SMILES: I[Nd](I)I
• Uses: Neodymium(III) iodide is used in glass coloring, permanent magnets, capacitors, infrared filters, resonators, catalysis (diene polymerization), laser materials.

Technology Process of Neodymium triiodide

There total 16 articles about Neodymium triiodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[Nd(water)9](I)3 → neodymium(III) iodide (13813-24-6)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Nd compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield: 74.0%

neodymium(II) diiodide + water (7732-18-5) → Nd(3+)*I(1-)*2OH(1-)*H2O=NdI(OH)2*H2O + hydrogen (1333-74-0) + neodymium(III) iodide (13813-24-6)

Guidance literature:

In water; under Ar; H2O added dropwise to NdI2 at 0°C; centrifugation, decantation, solid washed with MeOH, dried under vac.; elem. anal.; Kinetics;

DOI:10.1007/s11172-007-0304-9

Reference yield:

2NH4(1+)*NdI5(2-)=(NH4)2NdI5 → ammonia (7664-41-7) + hydrogen iodide (10034-85-2) + neodymium(III) iodide (13813-24-6)

Guidance literature:

In neat (no solvent); total decompn. at ca. 410°C;

upstream raw materials:

hydrogen iodide

aluminium(III) iodide

carbon monoxide

iodine

Downstream raw materials:

uranium(III) triiodide

Nd(C₆H₅N₂C₃(CH₃)2(CHO)O)4I₂⁽¹⁺⁾*I^(1-)=[Nd(C₆H₅N₂C₃(CH₃)2(CHO)O)4I₂]I

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